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Tricarbonyl-chlorido{N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine-?N,P}rhenium(I) dichloro-methane solvate.

ABSTRACT: In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa-hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine ligand. The compound crystallizes with one CH(2)Cl(2) mol-ecule per asymmetric unit. The benzyl-amine ligand and the Re(I) centre form a non-planar six-membered chelate ring.

SUBMITTER: Monkowius U

PROVIDER: S-EPMC2960194 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Tricarbonyl-chlorido{N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine-κN,P}rhenium(I) dichloro-methane solvate.

Monkowius Uwe U Zabel Manfred M

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa-hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine ligand. The compound crystallizes with one CH(2)Cl(2) mol-ecule per asymmetric unit. The benzyl-amine ligand and the Re(I) centre form a non-planar six-membered chelate ring. ...[more]

PMID: 21201284

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