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[1,3-Bis(diphenyl-phosphino)propane-?P,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate.

ABSTRACT: The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110?(2)?K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh-C bond is relatively short at 1.996?(6)?Å. This short metal-carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds.

SUBMITTER: Panthi B

PROVIDER: S-EPMC2959266 | biostudies-literature | 2008 Sep

REPOSITORIES: biostudies-literature

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[1,3-Bis(diphenyl-phosphino)propane-κP,P']diiodido(perfluoro-propyl)rhodium(III) dichloro-methane solvate.

Panthi Basu B Gipson Stephen L SL Franken Andreas A

Acta crystallographica. Section E, Structure reports online 20080927 Pt 10

The structure of the title compound, [RhI(2)(C(3)F(7))(C(27)H(26)P(2))]·CH(2)Cl(2), at 110 (2) K is an unusual example of a structurally characterized square-based pyramidal alkyl complex of rhodium(III). The Rh-C bond is relatively short at 1.996 (6) Å. This short metal-carbon bond length is typical of perfluoro complexes of transition metals and illustrates the enhanced bond strength in these compounds. ...[more]

PMID: 21201064

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