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Aqua-bis(o-vanillinato-?O,O')nickel(II).

ABSTRACT: The Ni(II) atom in the title complex, aqua-bis(2-formyl-6-meth-oxy-phenolato-?(2)O,O')nickel(II), [Ni(C(8)H(7)O(3))(2)(H(2)O)], is five-coordinated by four O atoms from two o-vanillinate ligands and one water mol-ecule in a slightly distorted square-pyramidal geometry (? = 0.06). In the crystal structure, the mol-ecules are linked into dimers by inter-molecular O-H?O hydrogen bonds.

SUBMITTER: Wang Q

PROVIDER: S-EPMC2960227 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Aqua-bis(o-vanillinato-κO,O')nickel(II).

Wang Qiang Q Wang Da-Qi DQ

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

The Ni(II) atom in the title complex, aqua-bis(2-formyl-6-meth-oxy-phenolato-κ(2)O,O')nickel(II), [Ni(C(8)H(7)O(3))(2)(H(2)O)], is five-coordinated by four O atoms from two o-vanillinate ligands and one water mol-ecule in a slightly distorted square-pyramidal geometry (τ = 0.06). In the crystal structure, the mol-ecules are linked into dimers by inter-molecular O-H⋯O hydrogen bonds. ...[more]

PMID: 21201274

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