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Aqua-(9,10-dioxoanthracene-1,5-disul-fonato-?O)bis-(1,10-phenanthroline-?N,N')nickel(II).

ABSTRACT: In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H?O hydrogen bond occurs. In the crystal, inter-molecular O-H?O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Furthermore, ?-? stacking inter-actions [centroid-centroid distance = 3.5696?(6)?Å] stabilize the crystal structuure.

SUBMITTER: Cao YY 

PROVIDER: S-EPMC2983167 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Aqua-(9,10-dioxoanthracene-1,5-disul-fonato-κO)bis-(1,10-phenanthroline-κN,N')nickel(II).

Cao Ying-Yu YY  

Acta crystallographica. Section E, Structure reports online 20100904 Pt 10

In the mononuclear title complex, [Ni(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)(H(2)O)], the Ni(II) atom is in a distorted octa-hedral coordination formed by four N atoms from two chelating 1,10-phenanthroline ligands and by two O atoms, one from a 9,10-dioxoanthracene-1,5-disulfonate ligand and the other from a water mol-ecule. An intra-molecular O-H⋯O hydrogen bond occurs. In the crystal, inter-molecular O-H⋯O hydrogen bonds link the mononuclear complexes into chains extending parallel to [010]. Fu  ...[more]

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