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4,4-Bis(4-methyl-phenyl-sulfan-yl)-1,1-diphenyl-2-aza-buta-1,3-diene.

ABSTRACT: In the title compound, C(29)H(25)NS(2), both the Cl atoms of the aza-diene precursor 4,4-dichloro-1,1-diphenyl-2-aza-buta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a ?-conjugated 2-aza-butadiene array. The aza-diene chain is planar to within 0.01?Å. One of the phenyl rings seems to be slightly ?-conjugated with the aza-diene core [dihedral angle 5.1?(2)°].

SUBMITTER: Kinghat R

PROVIDER: S-EPMC2960289 | biostudies-literature | 2008

REPOSITORIES: biostudies-literature

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4,4-Bis(4-methyl-phenyl-sulfan-yl)-1,1-diphenyl-2-aza-buta-1,3-diene.

Kinghat Rodolphe R Boudiba Hamid H Khatyr Abderrahim A Knorr Michael M Kubicki Marek M MM

Acta crystallographica. Section E, Structure reports online 20080104 Pt 2

In the title compound, C(29)H(25)NS(2), both the Cl atoms of the aza-diene precursor 4,4-dichloro-1,1-diphenyl-2-aza-buta-1,3-diene are replaced by two vicinal S-p-tolyl substituents attached to the terminal C atom of a π-conjugated 2-aza-butadiene array. The aza-diene chain is planar to within 0.01 Å. One of the phenyl rings seems to be slightly π-conjugated with the aza-diene core [dihedral angle 5.1 (2)°]. ...[more]

PMID: 21201402

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