Unknown

Dataset Information

0

Catena-Poly[[[aqua-(propane-1,3-diamine-?N,N')copper(II)]-?-fumarato-?O:O'] monohydrate].

ABSTRACT: The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873?(3)?Å] is to a water mol-ecule bridging equivalent Cu(II) atoms in adjacent chains, forming a three-dimensional framework. One of the Cu(II) atoms is in a distorted square-pyramidal environment and the other is in a pseudo-octa-hedral geometry of the [5+1] type. O-H?O and N-H?O hydrogen bonds are observed in the crystal structure.

SUBMITTER: Padmanabhan M 

PROVIDER: S-EPMC2960309 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[aqua-(propane-1,3-diamine-κN,N')copper(II)]-μ-fumarato-κO:O'] monohydrate].

Padmanabhan M M   Joseph James C JC   Olsson Susanne S   Bakir Mohammed M  

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

The asymmetric unit of the title compound, {[Cu(C(4)H(2)O(4))(C(3)H(10)N(2))(H(2)O)]·H(2)O}(n), consists of two Cu(II) atoms, half each of two propane-1,3-diamine ligands and two coordinated water mol-ecules, all lying on crystallographic mirror planes, also one fumarate dianion and one uncoordinated water mol-ecule in a general position. The Cu(C(3)H(10)N(2))(H(2)O) units are linked via fumarate dianions into a zigzag chain running along the a axis. A longer Cu-O distance [2.873 (3) Å] is to a  ...[more]

Similar Datasets

Unknown catena-Poly[[aqua-dipyridine-copper(II)]-μ-fumarato].
| S-EPMC2914965 | biostudies-literature
Unknown catena-Poly[[[diaqua-copper(II)]-bis-[?(2)-1,3-bis-(1,2,4-triazol-1-yl)propane]] dinitrate monohydrate].
| S-EPMC2970232 | biostudies-literature
Unknown Oxalatobis(propane-1,3-diamine)manganese(II) chloride monohydrate.
| S-EPMC2915106 | biostudies-literature
Unknown Diazido-bis(propane-1,3-diamine)copper(II).
| S-EPMC2984027 | biostudies-literature
Unknown catena-Poly[[aqua-(1,10-phenanthroline)cobalt(II)]-?-4,4'-(propane-1,3-diyldi-oxy)dibenzoato].
| S-EPMC2970340 | biostudies-literature
Unknown catena-Poly[[[aqua-(1,10-phenanthro-line)manganese(II)]-μ-adamantane-1,3-dicarboxyl-ato] monohydrate].
| S-EPMC3246965 | biostudies-literature
Unknown catena-Poly[[tetra-aqua-copper(II)]-?-tri-thionato-?O:O'].
| S-EPMC2972059 | biostudies-literature
Unknown catena-Poly[[aqua-(imidazole)-cadmium(II)]-?(3)-benzene-1,3-dicarboxyl-ato].
| S-EPMC3006711 | biostudies-literature
Unknown Diacetatobis(propane-1,3-diamine)nickel(II) dihydrate.
| S-EPMC2984075 | biostudies-literature
Unknown Bis[tris(propane-1,3-diamine-?(2) N,N')-nickel(II)] di-aqua-bis(propane-1,3-di-amine-?(2) N,N')nickel(II) hexa-bromide dihydrate.
| S-EPMC4051000 | biostudies-literature