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(Acetyl-acetonato-?O,O')-aqua-[salicyl-aldehyde nicotinoylhydrazonato(2-)-?O,N,O']manganese(III).

ABSTRACT: The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetyl-acetonate anion and a water mol-ecule in a distorted octa-hedral geometry. There is an extended two-dimensional supra-molecular motif resulting from O-H?N hydrogen bonds between the coordinated water mol-ecule and a hydrazine N or pyridine N atom, and from C-H?O hydrogen bonds between a CH group and the phenolate O atom.

SUBMITTER: Wang ZY

PROVIDER: S-EPMC2960424 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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(Acetyl-acetonato-κO,O')-aqua-[salicyl-aldehyde nicotinoylhydrazonato(2-)-κO,N,O']manganese(III).

Wang Zeng-You ZY Liu Shi-Xiong SX Fu Zhong-Wu ZW

Acta crystallographica. Section E, Structure reports online 20080118 Pt 2

The Mn(III) atom in the title complex, [Mn(C(13)H(9)N(3)O(2))(C(5)H(7)O(2))(H(2)O)], is coordinated by three donors from a dianionic ligand, salicylaldehyde nicotylhydrazone, two O atoms from an acetyl-acetonate anion and a water mol-ecule in a distorted octa-hedral geometry. There is an extended two-dimensional supra-molecular motif resulting from O-H⋯N hydrogen bonds between the coordinated water mol-ecule and a hydrazine N or pyridine N atom, and from C-H⋯O hydrogen bonds between a CH group a ...[more]

PMID: 21201327

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