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Trans-Tetra-aqua-bis[3-(3-pyrid-yl)acrylato-?N]cobalt(II).


ABSTRACT: The asymmetric unit of the title compound, [Co(C(8)H(6)NO(2))(2)(H(2)O)(4)], contains one half-mol-ecule. The Co(II) atom lies on an inversion centre and is coordinated by two N atoms of the pyridine rings of 3-(3-pyrid-yl)acrylate anions and four O atoms of water mol-ecules in a distorted octa-hedral coordination geometry. In the crystal structure, inter-molecular O-H?O hydrogen bonds link the mol-ecules, forming a three-dimensional network.

SUBMITTER: Miklovic J 

PROVIDER: S-EPMC2960429 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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trans-Tetra-aqua-bis[3-(3-pyrid-yl)acrylato-κN]cobalt(II).

Miklovič Jozef J   Moncol Jan J   Mikloš Dušan D   Segľa Peter P   Koman Marian M  

Acta crystallographica. Section E, Structure reports online 20080130 Pt 2


The asymmetric unit of the title compound, [Co(C(8)H(6)NO(2))(2)(H(2)O)(4)], contains one half-mol-ecule. The Co(II) atom lies on an inversion centre and is coordinated by two N atoms of the pyridine rings of 3-(3-pyrid-yl)acrylate anions and four O atoms of water mol-ecules in a distorted octa-hedral coordination geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules, forming a three-dimensional network. ...[more]

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