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Hexakis(2-amino-4-methyl-pyridine-?N)dioxidohexa-?(4)-sulfido-hexa-copper(I)divanadium(V).

ABSTRACT: The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra-hedra, forming an octa-nuclear V/S/Cu cluster with C(i) symmetry. The geometry around the V atoms is slightly distorted tetra-hedral, while there are large distortions from ideal tetra-hedral geometry for the Cu atoms. Adjacent metal-metal distances range from 2.693?(1) to 2.772?(10)?Å, indicating weak metal-metal inter-actions in the cluster.

SUBMITTER: Yu Z

PROVIDER: S-EPMC2960477 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Hexakis(2-amino-4-methyl-pyridine-κN)dioxidohexa-μ(4)-sulfido-hexa-copper(I)divanadium(V).

Yu Zhang Z Tang Guodong G Zhao Jianying J Jiang Zhengjing Z

Acta crystallographica. Section E, Structure reports online 20080830 Pt 9

The title compound, [Cu(6)V(2)O(2)S(6)(C(6)H(8)N(2))(6)], is constructed from six CuS(3)N and two VOS(3) distorted tetra-hedra, forming an octa-nuclear V/S/Cu cluster with C(i) symmetry. The geometry around the V atoms is slightly distorted tetra-hedral, while there are large distortions from ideal tetra-hedral geometry for the Cu atoms. Adjacent metal-metal distances range from 2.693 (1) to 2.772 (10) Å, indicating weak metal-metal inter-actions in the cluster. ...[more]

PMID: 21201649

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