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Hexa-?(2)-chlorido-?(4)-oxido-tetra-kis-[(3-methyl-5-phenyl-1H-pyrazole-?N)copper(II)].

ABSTRACT: The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl-pyrazole ligand, three Cl(-) anions, and one O(2-) anion. The geometry at each Cu(II) atom is distorted trigonal-bipyramidal, with the three Cl(-) ions in the equatorial plane and the N and O atoms in the axial positions.

SUBMITTER: He H

PROVIDER: S-EPMC3051691 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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Hexa-μ(2)-chlorido-μ(4)-oxido-tetra-kis-[(3-methyl-5-phenyl-1H-pyrazole-κN)copper(II)].

He Hongshan H

Acta crystallographica. Section E, Structure reports online 20110108 Pt 2

The title compound, [Cu(4)Cl(6)O(C(10)H(10)N(2))(4)], contains four Cu(II) atoms which are bridged by six chloride anions. The central O atom is located on a crystallographic fourfold roto-inversion axis. Each Cu(II) atom is coordinated by an N atom of a neutral monodentate 3-methyl-5-phenyl-pyrazole ligand, three Cl(-) anions, and one O(2-) anion. The geometry at each Cu(II) atom is distorted trigonal-bipyramidal, with the three Cl(-) ions in the equatorial plane and the N and O atoms in the ax ...[more]

PMID: 21522826

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