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Trans-Dibromidobis(3-methyl-pyridine-?N)copper(II).

ABSTRACT: The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol-ecule, the whole mol-ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu?Br bonds [3.269?(1)?Å] and nonclassical C-H?Br hydrogen bonds connect the mol-ecules, forming chains running parallel to the a axis. These chains are further linked via additional C-H?Br hydrogen bonds into a three-dimensional network.

SUBMITTER: Awwadi FF

PROVIDER: S-EPMC3569207 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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trans-Dibromidobis(3-methyl-pyridine-κN)copper(II).

Awwadi Firas F FF

Acta crystallographica. Section E, Structure reports online 20130119 Pt 2

The asymmetric unit of the title compound, [CuBr(2)(C(6)H(7)N)(2)], contains one half-mol-ecule, the whole mol-ecule being generated by inversion through a center located at the Cu(II) atom. The geometry around the Cu(II) atom is square planar. Semicoordinate Cu⋯Br bonds [3.269 (1) Å] and nonclassical C-H⋯Br hydrogen bonds connect the mol-ecules, forming chains running parallel to the a axis. These chains are further linked via additional C-H⋯Br hydrogen bonds into a three-dimensional network. ...[more]

PMID: 23424409

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