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{2-[(2,5-Dimethyl-phen-yl)imino-methyl]pyridine-?N,N'}diiodidozinc(II).

ABSTRACT: In the mol-ecule of the title compound, [ZnI(2)(C(14)H(14)N(2))], the Zn atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The benzene and pyridine rings are oriented at a dihedral angle of 70.75?(3)°. The five-membered ring has an envelope conformation. There is a weak ?-? inter-action between benzene rings, with a centroid-to-centroid distance of 3.975?(4)?Å.

SUBMITTER: Talei Bavil Olyai MR

PROVIDER: S-EPMC2960630 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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{2-[(2,5-Dimethyl-phen-yl)imino-methyl]pyridine-κN,N'}diiodidozinc(II).

Talei Bavil Olyai Mohamad Reza MR Dehghanpour Saeed S Hoormehr Bita B Gholami Fahimeh F Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20080823 Pt 9

In the mol-ecule of the title compound, [ZnI(2)(C(14)H(14)N(2))], the Zn atom is four-coordinated in a distorted tetra-hedral geometry by two N atoms of the Schiff base ligand and by two I atoms. The benzene and pyridine rings are oriented at a dihedral angle of 70.75 (3)°. The five-membered ring has an envelope conformation. There is a weak π-π inter-action between benzene rings, with a centroid-to-centroid distance of 3.975 (4) Å. ...[more]

PMID: 21201630

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