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Dichlorido{2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc.

ABSTRACT: In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra-hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine and two chloride anions. In the crystal, adjacent mol-ecules are connected through C-H?Cl hydrogen bonds between a C-H group of the ligand and a Cl(-) anion, leading to a chain-like structure along the b direction.

SUBMITTER: Liu XH

PROVIDER: S-EPMC3297262 | biostudies-literature | 2012 Mar

REPOSITORIES: biostudies-literature

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Dichlorido{2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc.

Liu Xue-Hong XH Zhao Li-Min LM Liu Feng-Shou FS

Acta crystallographica. Section E, Structure reports online 20120224 Pt 3

In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra-hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine and two chloride anions. In the crystal, adjacent mol-ecules are connected through C-H⋯Cl hydrogen bonds between a C-H group of the ligand and a Cl(-) anion, leading to a chain-like structure along the b direction. ...[more]

PMID: 22412452

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