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Aqua-(hexa-methyl-enetetra-mine-?N)bis-(methanol-?O)bis-(thio-cyanato-?N)cobalt(II).

ABSTRACT: In the title complex, [Co(NCS)(2)(C(6)H(12)N(4))(CH(4)O)(2)(H(2)O)], the six-coordinated Co atom has a slightly distorted octa-hedral geometry. The molecules are linked by intermolecular O-H?S and O-H?N hydrogen bonds, forming a three- dimensional crystal structure. Intramolecular C-H?N and C-H?O hydrogen bonds are also present.

SUBMITTER: Shang WL

PROVIDER: S-EPMC2960658 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Aqua-(hexa-methyl-enetetra-mine-κN)bis-(methanol-κO)bis-(thio-cyanato-κN)cobalt(II).

Shang Wei-Li WL Bai Yan Y Ma Chao-Zhong CZ Li Zhi-Min ZM

Acta crystallographica. Section E, Structure reports online 20080820 Pt 9

In the title complex, [Co(NCS)(2)(C(6)H(12)N(4))(CH(4)O)(2)(H(2)O)], the six-coordinated Co atom has a slightly distorted octa-hedral geometry. The molecules are linked by intermolecular O-H⋯S and O-H⋯N hydrogen bonds, forming a three- dimensional crystal structure. Intramolecular C-H⋯N and C-H⋯O hydrogen bonds are also present. ...[more]

PMID: 21201625

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