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Triclinic modification of di-n-butyl-bis(2-hydroxy-benzoato-?O,O)tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(5)O(3))(2)], is chelated by the carboxyl-ate groups of 2-hydroxy-benzoate liagnds, and exists in a six-coordinate skew-trapezoidal bipyramidal coordination geometry [C-Sn-C = 140.1?(3)°].

SUBMITTER: Reisi R

PROVIDER: S-EPMC2960726 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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Triclinic modification of di-n-butyl-bis(2-hydroxy-benzoato-κO,O)tin(IV).

Reisi Reza R Misran Misni M Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080820 Pt 9

The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(5)O(3))(2)], is chelated by the carboxyl-ate groups of 2-hydroxy-benzoate liagnds, and exists in a six-coordinate skew-trapezoidal bipyramidal coordination geometry [C-Sn-C = 140.1 (3)°]. ...[more]

PMID: 21201627

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Octa-butyl-bis-(?(2)-2-chloro-5-nitro-benzoato)bis-(2-chloro-5-nitro-benzoato)di-?(3)-oxido-tetra-tin(IV).

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Crystal structure of bis-(benzoato-?O)di-butyl-tin(IV), nBu2Sn(bzo)2.

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| S-EPMC3051678 | biostudies-literature

Bis(N-benzyl-N-isopropyl-dithio-carbamato-κS)di-n-butyl-tin(IV).

Project description:The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(11)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bonded S atoms. The C(2)Sn angles range from 129.0 (2) to 136.9 (2)°, the covalent Sn-S lengths from 2.529 (1) to 2.544 (1) Å, and the dative Sn←S lengths from 2.831 (1) to 3.042 (1) Å in the five independent mol-ecules comprising the asymmetric unit. Two of the butyl groups were modelled over two positions of equal occupancy. All butyl groups were refined with distance restraints.

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Di-n-butyl-bis-(N-ethyl-N-phenyl-dithio-carbamato-κS)tin(IV).

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| S-EPMC2983955 | biostudies-literature

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