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Di-n-butyl-bis(N-n-butyl-N-ethyl-dithio-carbamato-?S)tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn-S = 2.521?(2) and Sn?S = 2.933?(2)?Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithio-carbamate unit are disordered about another mirror plane.

SUBMITTER: Baba I

PROVIDER: S-EPMC2977630 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Di-n-butyl-bis(N-n-butyl-N-ethyl-dithio-carbamato-κS)tin(IV).

Baba Ibrahim I Dzulkefli Nur Nadia NN Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20090430 Pt 5

The Sn atom in the title compound, [Sn(C(4)H(9))(2)(C(7)H(14)NS(2))(2)], exists in a tetra-hedral C(2)S(2)Sn coordination geometry. The geometry is distorted towards skew-trapezoidal-bipyramidal owing to the proximity of the double-bond S atoms [Sn-S = 2.521 (2) and Sn⋯S = 2.933 (2) Å]. The Sn atom lies on a special position of mm2 site symmetry and the tin-bound n-butyl chain is disordered about a mirror plane. The ethyl and n-butyl groups of the dithio-carbamate unit are disordered about anoth ...[more]

PMID: 21583816

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