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(Methanol-?O)(methano-lato-?O)oxido[N-(2-oxidobenzyl-idene)phenyl-alaninato-?O,N,O']vanadium(V).

ABSTRACT: In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicyl-aldehyde and l-phenyl-alanine, a vanadyl O atom, a methano-late O atom and a methanol O atom, forming a distorted octa-hedral coordination geometry. In the crystal, inter-molecular O-H?O and C-H?O hydrogen bonds result in a two-dimensional structure parallel to (001).

SUBMITTER: Bian L

PROVIDER: S-EPMC3051455 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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(Methanol-κO)(methano-lato-κO)oxido[N-(2-oxidobenzyl-idene)phenyl-alaninato-κO,N,O']vanadium(V).

Bian Lin L Li Lianzhi L

Acta crystallographica. Section E, Structure reports online 20110129 Pt 2

In the title complex, [V(C(16)H(13)NO(3))(CH(3)O)O(CH(3)OH)], the V(V) atom is six-coordinated by a tridentate ligand derived from the condensation of salicyl-aldehyde and l-phenyl-alanine, a vanadyl O atom, a methano-late O atom and a methanol O atom, forming a distorted octa-hedral coordination geometry. In the crystal, inter-molecular O-H⋯O and C-H⋯O hydrogen bonds result in a two-dimensional structure parallel to (001). ...[more]

PMID: 21522922

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