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Diaqua-bis(benzyl-oxyacetato)copper(II).


ABSTRACT: In the title mononuclear complex, [Cu(C(9)H(9)O(3))(2)(H(2)O)(2)], the Cu(II) ion, located on an inversion center, is hexa-coordinated by four O atoms from two benzyl-oxyacetate ligands [Cu-O = 1.9420?(14) and 2.2922?(14)?Å] and two water mol-ecules [Cu-O = 2.0157?(15)?Å] in a distorted octa-hedral geometry. In the crystal structure, inter-molecular O-H?O hydrogen bonds link the mol-ecules into layers parallel to the bc plane.

SUBMITTER: Sun SL 

PROVIDER: S-EPMC2961141 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Diaqua-bis(benzyl-oxyacetato)copper(II).

Sun Sheng-Li SL   Chen Chun-Liang CL   Gu Chang-Sheng CS   Song Weng-Dong WD   Hao Xiao-Min XM  

Acta crystallographica. Section E, Structure reports online 20080423 Pt 5


In the title mononuclear complex, [Cu(C(9)H(9)O(3))(2)(H(2)O)(2)], the Cu(II) ion, located on an inversion center, is hexa-coordinated by four O atoms from two benzyl-oxyacetate ligands [Cu-O = 1.9420 (14) and 2.2922 (14) Å] and two water mol-ecules [Cu-O = 2.0157 (15) Å] in a distorted octa-hedral geometry. In the crystal structure, inter-molecular O-H⋯O hydrogen bonds link the mol-ecules into layers parallel to the bc plane. ...[more]

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