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Diaqua-bis[2-(benzyl-oxy)acetato]cobalt(II).

ABSTRACT: In the mononuclear title complex, [Co(C(9)H(9)O(3))(2)(H(2)O)(2)], each Co(II) atom is located on an inversion center and is hexa-coordinated by four O atoms from two benzyl-oxyacetate ligands [Co-O bond lengths = 2.0487?(9) and 2.1090?(9)?Å] and two water mol-ecules [Co-O bond length = 2.0873?(9)?Å] in a distorted octa-hedral geometry. In the crystal structure, inter-molecular hydrogen bonds and ?-? stacking inter-actions [centroid-centroid distance between phenyl rings = 3.692?(2)?Å] link the mol-ecules into a supra-molecular structure.

SUBMITTER: Chen CL 

PROVIDER: S-EPMC2961700 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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Diaqua-bis[2-(benzyl-oxy)acetato]cobalt(II).

Chen Chun-Liang CL   Sun Sheng-Li SL   Gu Chang-Sheng CS   Song Weng-Dong WD   Hao Xiao-Min XM  

Acta crystallographica. Section E, Structure reports online 20080607 Pt 7

In the mononuclear title complex, [Co(C(9)H(9)O(3))(2)(H(2)O)(2)], each Co(II) atom is located on an inversion center and is hexa-coordinated by four O atoms from two benzyl-oxyacetate ligands [Co-O bond lengths = 2.0487 (9) and 2.1090 (9) Å] and two water mol-ecules [Co-O bond length = 2.0873 (9) Å] in a distorted octa-hedral geometry. In the crystal structure, inter-molecular hydrogen bonds and π-π stacking inter-actions [centroid-centroid distance between phenyl rings = 3.692 (2) Å] link the  ...[more]

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