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Diaqua-bis-(perchlorato)(1,10-phenanthroline)copper(II).

ABSTRACT: In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water mol-ecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octa-hedral environment. The crystal packing is stabilized by O-H?O hydrogen bonds between the water mol-ecules and the perchlorate anions. In addition, the organic mol-ecules are associated by ?-? stacking inter-actions between symmetry-equivalent anti-parallel non-nitro-gen aromatic rings, with inter-planar distances of 3.543?(2)?Å.

SUBMITTER: Kaabi K

PROVIDER: S-EPMC3008125 | biostudies-literature | 2010 Aug

REPOSITORIES: biostudies-literature

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Diaqua-bis-(perchlorato)(1,10-phenanthroline)copper(II).

Kaabi Kamel K El Glaoui Meher M Zeller Matthias M Ben Nasr Cherif C

Acta crystallographica. Section E, Structure reports online 20100821 Pt 9

In the title compound, [Cu(ClO(4))(2)(C(12)H(8)N(2))(H(2)O)(2)], the Cu(II) atom is coordinated in a square-planar fashion by the two N atoms of a chelating 1,10-phenanthroline ligand and by two water mol-ecules trans to the N atoms. The coordination sphere of the metal atom is augmented by O atoms of two weakly bonded perchlorate anions, thus yielding a strongly distorted CuN(2)O(4) octa-hedral environment. The crystal packing is stabilized by O-H⋯O hydrogen bonds between the water mol-ecules a ...[more]

PMID: 21588543

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