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Aqua-[N-(1-naphth-yl)acetamido-κN]bis-[2-(2-pyrid-yl)phenyl-κN,C]iridium(III) ethyl-ene glycol hemisolvate.

ABSTRACT: In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid-yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth-yl)acetamide ligand and one water O atom, forming a distorted octa-hedral environment. Mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds formed by the coordinated water mol-ecule and the amide O atom of the N-(1-naphth-yl)acetamide ligands.

SUBMITTER: Fu H

PROVIDER: S-EPMC2961167 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Aqua-[N-(1-naphth-yl)acetamido-κN]bis-[2-(2-pyrid-yl)phenyl-κN,C]iridium(III) ethyl-ene glycol hemisolvate.

Fu Hao H Ding Yuqiang Y Chen Guoqing G

Acta crystallographica. Section E, Structure reports online 20080430 Pt 5

In the title compound, [Ir(C(11)H(8)N)(2)(C(12)H(10)NO)(H(2)O)]·0.5C(2)H(6)O(2), the iridium center is coordinated by two N atoms and two C atoms from two 2-(2-pyrid-yl)phenyl (ppy) ligands, one N atom from the N-(1-naphth-yl)acetamide ligand and one water O atom, forming a distorted octa-hedral environment. Mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds formed by the coordinated water mol-ecule and the amide O atom of the N-(1-naphth-yl)acetamide ligands. ...[more]

PMID: 21202254

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