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Cis-Dichloridobis[2-(hydroxy-meth-yl)tetra-hydro-furan-?O,O']manganese(II).

ABSTRACT: The structure of the title compound, [MnCl(2)(C(5)H(10)O(2))(2)], was solved from low-temperature data collected at 100?(2)?K. The asymmetric unit contains one half-mol-ecule with the Mn(II) ion located on a twofold axis. A distorted octa-hedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxy-methyl)tetra-hydro-furan ligands, and by two chloride ions. The chelating tetra-hydro-furan ligands, which form five-membered rings, are cis oriented. The crystal structure is stabilized by hydrogen bonding between the coordinated OH groups and the chloride ions.

SUBMITTER: Jerzykiewcz LB 

PROVIDER: S-EPMC2961271 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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cis-Dichloridobis[2-(hydroxy-meth-yl)tetra-hydro-furan-κO,O']manganese(II).

Jerzykiewcz Lucjan B LB   Utko Józef J   Sobota Piotr P  

Acta crystallographica. Section E, Structure reports online 20080410 Pt 5

The structure of the title compound, [MnCl(2)(C(5)H(10)O(2))(2)], was solved from low-temperature data collected at 100 (2) K. The asymmetric unit contains one half-mol-ecule with the Mn(II) ion located on a twofold axis. A distorted octa-hedral environment around the Mn atom is formed by two ether and two hydroxyl O atoms of two 2-(hydroxy-methyl)tetra-hydro-furan ligands, and by two chloride ions. The chelating tetra-hydro-furan ligands, which form five-membered rings, are cis oriented. The cr  ...[more]

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