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Trilithium scandium bis-(orthoborate).


ABSTRACT: Single crystals of the title compound, Li(3)Sc(BO(3))(2), have been obtained by spontaneous nucleation from a high-temperature melt. The title compound adopts a framework structure and is composed of distorted [ScO(6)] octa-hedra, [LiO(4)] tetra-hedra, [LiO(4)] recta-ngles and isolated [BO(3)] triangles. Except for the Sc and one Li atom (both on inversion centres), all atoms are in general positions.

SUBMITTER: Mao L 

PROVIDER: S-EPMC2961348 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Trilithium scandium bis-(orthoborate).

Mao Lizhong L   Zhou Tianyong T   Ye Ning N  

Acta crystallographica. Section E, Structure reports online 20080521 Pt 6


Single crystals of the title compound, Li(3)Sc(BO(3))(2), have been obtained by spontaneous nucleation from a high-temperature melt. The title compound adopts a framework structure and is composed of distorted [ScO(6)] octa-hedra, [LiO(4)] tetra-hedra, [LiO(4)] recta-ngles and isolated [BO(3)] triangles. Except for the Sc and one Li atom (both on inversion centres), all atoms are in general positions. ...[more]

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