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Poly[[?(3)-3-(3-pyrid-yl)acrylato-?N:O:O'][?(2)-3-(3-pyrid-yl)acrylato-?O,O':O][?(2)-3-(3-pyrid-yl)acrylato-?O:O')]gadolinium(III)].

ABSTRACT: In the title compound, [Gd(C(8)H(6)NO(2))(3)](n), the Gd(III) ion is in a bicapped trigonal prismatic coordination environment formed by seven O atoms and one N atom, derived from seven different 3-(3-pyrid-yl)acrylate (3-PYA) ligands. Gd(III) ions are bridged by bidentate and tridentate 3-PYA ligands, resulting in a two-dimensional structure.

SUBMITTER: Qiu ZH

PROVIDER: S-EPMC2961497 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Poly[[μ(3)-3-(3-pyrid-yl)acrylato-κN:O:O'][μ(2)-3-(3-pyrid-yl)acrylato-κO,O':O][μ(2)-3-(3-pyrid-yl)acrylato-κO:O')]gadolinium(III)].

Qiu Zhi-Hui ZH Liang Fu-Pei FP Ruan Qing-Feng QF Chen Zi-Lu ZL

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

In the title compound, [Gd(C(8)H(6)NO(2))(3)](n), the Gd(III) ion is in a bicapped trigonal prismatic coordination environment formed by seven O atoms and one N atom, derived from seven different 3-(3-pyrid-yl)acrylate (3-PYA) ligands. Gd(III) ions are bridged by bidentate and tridentate 3-PYA ligands, resulting in a two-dimensional structure. ...[more]

PMID: 21202459

Similar Datasets

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| S-EPMC3007524 | biostudies-literature

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Project description:In the title compound, [CuCl(2)(C(6)H(7)N)(2)(C(12)H(8)N(4)O)](n), the Cu atom, located on an inversion center, is coordinated by four N atoms from two aniline ligands and two 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands. Two Cl atoms lying above and below the plane formed by these four N atoms inter-act weakly with the Cu atom [Cu-Cl = 2.7870?(7)?Å]. The trans 2,5-bis-(4-pyrid-yl)-1,3,4-oxadiazole ligands act as bridging ligands, linking adjacent Cu atoms and forming a one-dimensional coordination polymer. Two anilines coordinate with each Cu atom as terminal groups. The structure contains two classical N-H?Cl and two non-classical C-H?Cl hydrogen bonds.

| S-EPMC2980127 | biostudies-literature

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