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Catena-Poly[[trimethyl-tin(IV)]-μ-[(E)-2-methyl-3-(3-methyl-phen-yl)acrylato-κO:O']].

ABSTRACT: The title trimethyl-tin(IV) carboxyl-ate, [Sn(CH(3))(3)(C(11)H(11)O(2))](n), is a carboxyl-ate-bridged polymer in which the Sn atom exists in a trans-C(3)SnO(2) trigonal bipyramidal coordination. One Sn-O bond is a covalent bond [2.114 (2) Å], whereas the other is a dative bond [2.607 (2) Å]. The polymeric chain propagates along the b axis of the monoclinic unit cell.

SUBMITTER: Muhammad N

PROVIDER: S-EPMC2961908 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyl-tin(IV)]-μ-[(E)-2-methyl-3-(3-methyl-phen-yl)acrylato-κO:O']].

Muhammad Niaz N Tahir M Nawaz MN Ali Saqib S Zia-Ur-Rehman

Acta crystallographica. Section E, Structure reports online 20080705 Pt 8

The title trimethyl-tin(IV) carboxyl-ate, [Sn(CH(3))(3)(C(11)H(11)O(2))](n), is a carboxyl-ate-bridged polymer in which the Sn atom exists in a trans-C(3)SnO(2) trigonal bipyramidal coordination. One Sn-O bond is a covalent bond [2.114 (2) Å], whereas the other is a dative bond [2.607 (2) Å]. The polymeric chain propagates along the b axis of the monoclinic unit cell. ...[more]

PMID: 21203077

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