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[?-1,4-Bis(diphenyl-phosphino-yl)butane-?O:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-?O)tin(IV)].

ABSTRACT: The mol-ecule of the dinuclear title compound, [Sn(2)(C(5)H(9))(2)(C(6)H(5))(4)(C(2)F(3)O(2))(2)(C(28)H(28)O(2)P(2))], lies on a center of inversion at the mid-point of the central C-C bond of the bridging phosphine oxide ligand. The Sn atom is five-coordinate in a trans-C(3)SnO(2) trigonal-bipyramidal geometry.

SUBMITTER: Teo YY

PROVIDER: S-EPMC2961610 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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[μ-1,4-Bis(diphenyl-phosphino-yl)butane-κO:O']bis-[cyclo-pentyl-diphen-yl(trifluoro-acetato-κO)tin(IV)].

Teo Yin Yin YY Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080510 Pt 6

The mol-ecule of the dinuclear title compound, [Sn(2)(C(5)H(9))(2)(C(6)H(5))(4)(C(2)F(3)O(2))(2)(C(28)H(28)O(2)P(2))], lies on a center of inversion at the mid-point of the central C-C bond of the bridging phosphine oxide ligand. The Sn atom is five-coordinate in a trans-C(3)SnO(2) trigonal-bipyramidal geometry. ...[more]

PMID: 21202479

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