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Benzoyl-methyl pyridine-4-carboxyl-ate.

ABSTRACT: In the crystal structure of the title compound, C(14)H(11)NO(3), isolated from the reaction of 2-bromo-1-phenyl-ethanone and pyridine-4-carboxylic acid using triethyl-amine as a base to deprotonate the organic acid, the mol-ecular packing is stabilized by C-H?? inter-actions involving the phenyl and pyridine rings. The C-C-O-C torsion angle for the linkage between the two carbonyl groups is -80.8?(2)°, and the planes of the phenyl and pyridyl rings form a dihedral angle of 65.8?(1)°.

SUBMITTER: Guo JN

PROVIDER: S-EPMC2961582 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Benzoyl-methyl pyridine-4-carboxyl-ate.

Guo Jian-Nan JN Zhang Bo-Chao BC Jin Yi Y Tang Guo G Zhao Yu-Fen YF

Acta crystallographica. Section E, Structure reports online 20080517 Pt 6

In the crystal structure of the title compound, C(14)H(11)NO(3), isolated from the reaction of 2-bromo-1-phenyl-ethanone and pyridine-4-carboxylic acid using triethyl-amine as a base to deprotonate the organic acid, the mol-ecular packing is stabilized by C-H⋯π inter-actions involving the phenyl and pyridine rings. The C-C-O-C torsion angle for the linkage between the two carbonyl groups is -80.8 (2)°, and the planes of the phenyl and pyridyl rings form a dihedral angle of 65.8 (1)°. ...[more]

PMID: 21202617

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