Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Hexa-?(2)-benzoato-bis-(2,2'-bipyrid-yl)trimanganese(II) monohydrate.

ABSTRACT: The complex molecule of the title compound, [Mn(3)(C(7)H(5)O(2))(6)(C(10)H(8)N(2))(2)]·H(2)O, contains a linear array of divalent manganese ions. The central Mn(II) atom, which is located on a crystallographic inversion center, is coordinated octa-hedrally by six benzoate O atoms. The two terminal Mn(II) ions are six-coordinated by four benzoate O atoms and two N atoms of 2,2'-bipyridyl. The central Mn(II) atom and the terminal Mn(II) ions are bridged by four benzoate ligands in a bidentate fashion, whereas the other two carboxyl-ate ligands form bridges through one O atom only and chelate the terminal Mn(II) atom. The mol-ecules pack together via van der Waals attractions and C-H?O hydrogen bonds.

SUBMITTER: Yao HC

PROVIDER: S-EPMC2961620 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Hexa-μ(2)-benzoato-bis-(2,2'-bipyrid-yl)trimanganese(II) monohydrate.

Yao Hong-Chang HC Wang Ning N Zhang Li L Li Zhong-Jun ZJ

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The complex molecule of the title compound, [Mn(3)(C(7)H(5)O(2))(6)(C(10)H(8)N(2))(2)]·H(2)O, contains a linear array of divalent manganese ions. The central Mn(II) atom, which is located on a crystallographic inversion center, is coordinated octa-hedrally by six benzoate O atoms. The two terminal Mn(II) ions are six-coordinated by four benzoate O atoms and two N atoms of 2,2'-bipyridyl. The central Mn(II) atom and the terminal Mn(II) ions are bridged by four benzoate ligands in a bidentate fash ...[more]

PMID: 21202466

Similar Datasets

cis-Bis-(2,2'-bipyrid-yl)dicyanato-cobalt(II).

Project description:In the title complex, [Co(NCO)(2)(C(10)H(8)N(2))(2)], the Co atom is coordinated by four N atoms from two 2,2'-bipyridyl ligands and two N atoms from two cyanate anions in a distorted octa-hedral geometry. The Co atom lies on a twofold rotation axis. The average Co-N bond length is 2.126 (7) Å. Weak inter-molecular C-H⋯O inter-actions lead to the formation of a three-dimensional network.

| S-EPMC2960999 | biostudies-literature

Bis(?-5-carboxyl-atotetra-zolido)bis-[aqua-(2,2'-bipyrid-yl)cadmium(II)].

Project description:In the title dinuclear Cd(II) complex, [Cd(2)(C(2)N(4)O(2))(2)(C(10)H(8)N(2))(2)(H(2)O)(2)], each Cd atom is in a slightly distorted octa-hedral coordination by two N atoms and one O atom of two 1H-tetra-zole-5-carboxyl-ate (TZC) ligands, two N atoms of a 2,2'-bipyridyl ligand and one water O atom. The TZC ligand acts in a tridentate N,O-chelating N-bridging mode to two symmetry-equivalent Cd(II) atoms. The complex reveals mol-ecular C(i) symmetry. Extensive O-H?O hydrogen bonding plays an important role in the crystal packing.

| S-EPMC3007395 | biostudies-literature

(2,2-Bipyrid-yl)bis-(?-penta-methyl-cyclo-penta-dien-yl)strontium(II).

Project description:In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr-N distances are 2.624?(3) and 2.676?(3)?Å, the Sr?Cp ring centroid distances are 2.571 and 2.561?Å and the N-C-C-N torsion angle in the bipyridine ligand is -2.2?(4)°. Inter-estingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7?(1)°.

| S-EPMC2960620 | biostudies-literature

Bis(2,2'-bipyrid-yl)(dichloro-acetato)copper(II) dichloro-acetate dihydrate.

Project description:In the title compound, [Cu(C(2)HCl(2)O(2))(C(10)H(8)N(2))(2)](C(2)HCl(2)O(2))·2H(2)O, the Cu(II) ion is bonded to two N,N'-bidentate 2,2'-bipyridyl ligands and one O-monodentate 2,2-dichloro-acetate anion in a distorted CuON(4) trigonal-bipyramidal geometry, with the O atom occupying an equatorial site. In the crystal, the components are linked by O-H?O and O-H?Cl hydrogen bonds.

| S-EPMC2979737 | biostudies-literature

Bis(2,2'-bipyrid-yl)bromidocopper(II) bromide bromo-acetic acid hemihydrate.

Project description:In the title compound, [CuBr(C(10)H(8)N(2))(2)]Br·BrCH(2)COOH·0.5H(2)O, the Cu(II) ion is coordinated by four N atoms [Cu-N = 1.985 (6)-2.125 (7) Å] from two 2,2'-bipyridine ligand mol-ecules and a bromide anion [Cu-Br = 2.471 (2) Å] in a distorted trigonal-bipyramidal geometry. Short centroid-centroid distances [3.762 (5) and 3.867 (5) Å] between the aromatic rings of neighbouring cations suggest the existence of π-π inter-actions. Inter-molecular O-H⋯Br hydrogen bonds and weak C-H⋯O and C-H⋯Br inter-actions consolidate the crystal packing.

| S-EPMC2971989 | biostudies-literature

Poly[hexa-?-acetato-bis-(dimethyl sulfoxide)-trimanganese(II)].

Project description:In the title complex, [Mn(3)(CH(3)CO(2))(6)(C(2)H(6)SO)(2)](n), the Mn(II) ions exhibit similar MnO(6) octa-hedral coordination geometries but with different coordination environments. One type of Mn(II) ion is surrounded by five acetate groups and a terminal dimethyl sulfoxide group, while the other lies on a twofold axis and is coordinated by six O atoms from three symmetry-related acetate ions. The acetate anions exhibit three independent bridging modes, which flexibly bridge the Mn(II) ions along the c-axis direction, forming an infinite chain structure; the chains are further inter-connected through weak C-H?O and C-H?S hydrogen-bonding inter-actions.

| S-EPMC3009130 | biostudies-literature

Poly[[bis-(2,2-bipyridine)-bis-[μ(6)-5-(carboxyl-atometh-oxy)benzene-1,3-dicarboxyl-ato]trimanganese(II)] monohydrate].

Project description:The title compound, {[Mn(3)(C(10)H(5)O(7))(2)(C(10)H(8)N(2))(2)]·H(2)O}(n), was synthesized under hydro-thermal conditions. Six carboxyl-ate groups of six 5-(carboxyl-atometh-oxy)benzene-1,3-dicarboxyl-ate anions (OABDC(3-)) join three Mn(II) ions into a trinuclear centrosymmetric [Mn(3)(μ(2)-COO)(6)] unit with one Mn site situated on a centre of inversion. The latter Mn(II) ion exhibits a distorted MnO(6) coordination, whereas the other Mn(II) ion has a trigonal-bipyramidal MnN(2)O(3) coordination environment resulting from three carboxylate O atoms and the two N atoms of the bipyridine ligand. Adjacent units are linked to each other by OABDC(3-) ligands into a layer parallel to (010). Within the layer, O-H⋯O hydrogen-bonding inter-actions involving the uncoordinated and half-occupied water mol-ecule and the free carboxyl-ate O atoms are observed. The layers stack along [010], constructing a three-dimensional structure through π-π inter-actions between adjacent pyridine rings, with a centroid-centroid distance of 3.473 (5) Å.

| S-EPMC3051434 | biostudies-literature

Diazido-(2,2'-bipyrid-yl)dimethanol-nickel(II).

Project description:The title complex, [Ni(N(3))(2)(C(10)H(8)N(2))(CH(3)OH)(2)], lies on a twofold roation axis which runs through the Ni(II) ion and the mid-point of the bipyridine ligand. The Ni(II) ion is coordinated in a distorted octa-hedral environment by two azide ligands in a trans configuration. The methanol ligands are in a cis configuration and their hy-droxy groups form intra-molecular O-H?(N,N) hydrogen bonds with the azide ligands.

| S-EPMC3009301 | biostudies-literature

catena-Poly[[[(2,2'-bipyrid-yl)copper(II)]-?-l-alaninato] perchlorate monohydrate].

Project description:In the structure of the polymeric title complex, {[Cu(C(3)H(6)NO(2))(C(10)H(8)N(2))]ClO(4)·H(2)O}(n), the carboxyl-ate group of the chelating amino acid is further linked to a neighbouring Cu centre, generating a supra-molecular single-stranded chain parallel to [010]. The structure displays inter-molecular N-H?O and O-H?O hydrogen bonding, which consolidates the crystal packing.

| S-EPMC2967894 | biostudies-other

Crystal structure of μ-oxalodi-hydroxamato-bis-[(2,2'-bipyrid-yl)(di-methyl sulfoxide-κO)copper(II)] bis-(perchlorate).

Project description:The centrosymmetric binuclear complex, [Cu2(C2H2N2O4)(C10H8N2)2(C2H6OS)2](ClO4)2, contains two copper(II) ions, connected through an N-deprotonated oxalodi-hydroxamic acid dianion, two terminal 2,2'-bi-pyridine ligands, and two apically coordinating dimethylsulfoxide mol-ecules. Two non-coordinating perchlorate anions assure electrical neutrality. The copper(II) ions in the complex dication [Cu2(C10H8N2)2(μ-C2H2N2O4)(C2H6SO)2](2+) are in an O2N3 square-pyramidal donor environment, the Cu-Cu separation being 5.2949 (4) Å. Two hydroxamate groups in the deprotonated oxalodi-hydroxamic acid are located trans to one each other. In the crystal, O-H⋯O and C-H⋯O hydrogen bonds link the complex cations to the perchlorate anions. Further C-H⋯O hydrogen bonds combine with π-π contacts with a centroid-to-centroid separation of 3.6371 (12) Å to stack the mol-ecules along the a-axis direction.

| S-EPMC4770973 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data