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Hexa-?(2)-benzoato-bis-(2,2'-bipyrid-yl)trimanganese(II) monohydrate.

ABSTRACT: The complex molecule of the title compound, [Mn(3)(C(7)H(5)O(2))(6)(C(10)H(8)N(2))(2)]·H(2)O, contains a linear array of divalent manganese ions. The central Mn(II) atom, which is located on a crystallographic inversion center, is coordinated octa-hedrally by six benzoate O atoms. The two terminal Mn(II) ions are six-coordinated by four benzoate O atoms and two N atoms of 2,2'-bipyridyl. The central Mn(II) atom and the terminal Mn(II) ions are bridged by four benzoate ligands in a bidentate fashion, whereas the other two carboxyl-ate ligands form bridges through one O atom only and chelate the terminal Mn(II) atom. The mol-ecules pack together via van der Waals attractions and C-H?O hydrogen bonds.

SUBMITTER: Yao HC

PROVIDER: S-EPMC2961620 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

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Hexa-μ(2)-benzoato-bis-(2,2'-bipyrid-yl)trimanganese(II) monohydrate.

Yao Hong-Chang HC Wang Ning N Zhang Li L Li Zhong-Jun ZJ

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

The complex molecule of the title compound, [Mn(3)(C(7)H(5)O(2))(6)(C(10)H(8)N(2))(2)]·H(2)O, contains a linear array of divalent manganese ions. The central Mn(II) atom, which is located on a crystallographic inversion center, is coordinated octa-hedrally by six benzoate O atoms. The two terminal Mn(II) ions are six-coordinated by four benzoate O atoms and two N atoms of 2,2'-bipyridyl. The central Mn(II) atom and the terminal Mn(II) ions are bridged by four benzoate ligands in a bidentate fash ...[more]

PMID: 21202466

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