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(2,2-Bipyrid-yl)bis-(?-penta-methyl-cyclo-penta-dien-yl)strontium(II).

ABSTRACT: In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr-N distances are 2.624?(3) and 2.676?(3)?Å, the Sr?Cp ring centroid distances are 2.571 and 2.561?Å and the N-C-C-N torsion angle in the bipyridine ligand is -2.2?(4)°. Inter-estingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7?(1)°.

SUBMITTER: Kazhdan D

PROVIDER: S-EPMC2960620 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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(2,2-Bipyrid-yl)bis-(η-penta-methyl-cyclo-penta-dien-yl)strontium(II).

Kazhdan Daniel D Hu Yung-Jin YJ Kokai Akos A Levi Zerubba Z Rozenel Sergio S

Acta crystallographica. Section E, Structure reports online 20080806 Pt 9

In the title compound, [Sr(C(10)H(15))(2)(C(10)H(8)N(2))], the Sr-N distances are 2.624 (3) and 2.676 (3) Å, the Sr⋯Cp ring centroid distances are 2.571 and 2.561 Å and the N-C-C-N torsion angle in the bipyridine ligand is -2.2 (4)°. Inter-estingly, the bipyridine ligand is tilted. The angle between the plane defined by the Sr atom and the two bipyridyl N atoms and the plane defined by the 12 atoms of the bipyridine ligand is 10.7 (1)°. ...[more]

PMID: 21201592

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