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2-Amino-N-(2-benz-yloxy-3-methoxy-benzyl-idene)aniline.


ABSTRACT: The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol-ecules (A and B) in the asymmetric unit, with similar conformations. In mol-ecule A, the central benzene ring forms dihedral angles of 30.79?(13) and 23.56?(13)°, respectively, with the amino and benzyl benzene rings, while in mol-ecule B these angles are 32.30?(13) and 13.13?(12)°. The mol-ecular structure is stabilized by intra-molecular N-H?N and C-H?O hydrogen bonds. The crystal structure is stabilized by N-H?N hydrogen bonds and N-H?? and C-H?? inter-actions.

SUBMITTER: Al-Douh MH 

PROVIDER: S-EPMC2961660 | biostudies-literature | 2008 Jun

REPOSITORIES: biostudies-literature

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2-Amino-N-(2-benz-yloxy-3-methoxy-benzyl-idene)aniline.

Al-Douh Mohammed H MH   Hamid Shafida A SA   Osman Hasnah H   Kia Reza R   Fun Hoong-Kun HK  

Acta crystallographica. Section E, Structure reports online 20080619 Pt 7


The title compound, C(21)H(20)N(2)O(2), a Schiff base ligand, contains two independent mol-ecules (A and B) in the asymmetric unit, with similar conformations. In mol-ecule A, the central benzene ring forms dihedral angles of 30.79 (13) and 23.56 (13)°, respectively, with the amino and benzyl benzene rings, while in mol-ecule B these angles are 32.30 (13) and 13.13 (12)°. The mol-ecular structure is stabilized by intra-molecular N-H⋯N and C-H⋯O hydrogen bonds. The crystal structure is stabilized  ...[more]

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