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Tris(ethyl-enediamine)-cobalt(III) diformatodioxalatoindate(III) dihydrate.

ABSTRACT: In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co-N bond lengths lie in the range 1.960?(5)-1.997?(5)?Å. In the anion, the In(III) atom is coordin-ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa-hedral geometry. Inter-molecular O-H?O and N-H?O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water mol-ecules into three-dimensional structure.

SUBMITTER: Tong J

PROVIDER: S-EPMC3089116 | biostudies-literature | 2011 May

REPOSITORIES: biostudies-literature

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Tris(ethyl-enediamine)-cobalt(III) diformatodioxalatoindate(III) dihydrate.

Tong Juying J Pan Qinhe Q

Acta crystallographica. Section E, Structure reports online 20110413 Pt 5

In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co-N bond lengths lie in the range 1.960 (5)-1.997 (5) Å. In the anion, the In(III) atom is coordin-ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa-hedral geometry. Inter-molecular O-H⋯O and N-H⋯O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water mol-ecules into three-dimensional structure. ...[more]

PMID: 21754305

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