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Tris(ethyl-enediamine)zinc(II) hexa-fluorido-silicate.

ABSTRACT: The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa-hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl-enediamine mol-ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2-) anions and the ethyl-enediamine NH hydrogen atoms.

SUBMITTER: Li Y

PROVIDER: S-EPMC2972015 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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Tris(ethyl-enediamine)zinc(II) hexa-fluorido-silicate.

Li Yang Y Shi Qi Q Shi Qi Q Slawin Alexandra M Z AM Woollins J Derek JD Dong Jinxiang J

Acta crystallographica. Section E, Structure reports online 20091107 Pt 12

The title compound, [Zn(C(2)H(8)N(2))(3)](SiF(6)), was synthesized ionothermally using choline chloride-imidazolidone as solvent and template provider. In the crystal structure, the anions and cations are located on special positions of site symmetry 3.2 and show a typical octa-hedral geometry. The Zn(II) ion is coordinated by six N atoms from three ethyl-enediamine mol-ecules. The crystal structure displays weak hydrogen bonding between [SiF(6)](2-) anions and the ethyl-enediamine NH hydrogen a ...[more]

PMID: 21578568

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Tris(ethyl-enediamine)zinc(II) dichloride monohydrate.

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Tris(ethyl-enediamine-?N,N')nickel(II) naphthalene-2,7-disulfonate.

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Project description:In the title compound, [Zn(C(15)H(11)N(2)O(2))(2)(C(2)H(8)N(2))], the Zn(II) atom is coordinated in a distorted tetra-hedral geometry. Intra-molecular N-H?O, C-H?O and C-H?N hydrogen bonds occur. In the crystal, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming a three-dimensional network.

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Tris(ethyl-enediamine)-nickel(II) 1H-pyrazole-3,5-dicarboxyl-ate 1.67-hydrate.

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Tris(ethyl-enediamine)-cobalt(III) diformatodioxalatoindate(III) dihydrate.

Project description:In the cation of the title compound, [Co(C(2)H(8)N(2))(3)][In(C(2)O(4))(2)(CHO(2))(2)]·2H(2)O, the Co-N bond lengths lie in the range 1.960?(5)-1.997?(5)?Å. In the anion, the In(III) atom is coordin-ated by four O atoms from two oxalato ligands and two O atoms from two formato ligands in a distorted octa-hedral geometry. Inter-molecular O-H?O and N-H?O hydrogen bonds form an extensive hydrogen-bonding network, which link the cations, anions and water mol-ecules into three-dimensional structure.

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[N-(2-Hydroxy-ethyl)ethyl-enediamine]oxalatocopper(II).

Project description:In the title mononuclear copper(II) compound, [Cu(C(2)O(4))(C(4)H(12)N(2)O)], the Cu(II) ion has a slightly distorted square-pyramidal geometry, with a tridentate N-(2-hydroxy-ethyl)ethyl-enediamine (HydEt-en) and a bidentate oxalate (ox) ligand. The N atoms of the HydEt-en ligand and the O atoms of ox ligand form the basal plane, while the O atom of the ethanol group of the HydEt-en ligand is located in the axial position. The complex mol-ecules participate in a supra-molecular assembly through N-H⋯O and O-H⋯O hydrogen bonds between HydEt-en and ox ligands.

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