Browse
Submit Data
Databases
API
Help

Dataset Information

25 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[aqua-trimethyl-tin(IV)]-{[trimethyl-tin(IV)]-?(3)-thio-phene-2,5-dicarboxyl-ato}].

ABSTRACT: In the title compound, [Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O)](n), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H?O hydrogen bonding.

SUBMITTER: Yang SX

PROVIDER: S-EPMC2968262 | biostudies-literature | 2009 Jan

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[aqua-trimethyl-tin(IV)]-{[trimethyl-tin(IV)]-μ(3)-thio-phene-2,5-dicarboxyl-ato}].

Yang Sheng-Xiang SX Li Yue-Zhong YZ Jiang Kun K

Acta crystallographica. Section E, Structure reports online 20090108 Pt 2

In the title compound, [Sn(2)(CH(3))(6)(C(6)H(2)O(4)S)(H(2)O)](n), each of the two crystallographically independent Sn atoms exhibits a distorted trigonal-bipyramidal coordination geometry formed by two O and three C atoms. The coordinated water mol-ecule plays an important role in crystal packing consolidation via O-H⋯O hydrogen bonding. ...[more]

PMID: 21581753

Similar Datasets

Poly[tetra-aqua-bis-(μ(4)-thio-phene-2,5-dicarboxyl-ato)(μ(2)-thio-phene-2,5-dicarboxyl-ato)dieuropium(III)].

Project description:The three-dimensional coordination polymer, [Eu(2)(C(6)H(2)O(4)S)(3)(H(2)O)(4)](n), has been synthesized under hydro-thermal conditions. The asymmetric unit comprises one Eu(3+) cation, two aqua ligands and one and a half thiophene-2,5-dicarboxylate anions (the half-anion being completed by a twofold rotation axis). The Eu(3+) cation is eight-coordinated in a distorted dodeca-hedral geometry. The crystal structure features O-H⋯O hydrogen bonds.

| S-EPMC3414099 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-5-methyl-thio-phene-2-carboxyl-ato-?O:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].

| S-EPMC3238733 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2-phenyl-butano-ato].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(10)H(11)O(2))](n), the Sn atom has a distorted trigonal-bipyramidal coordination geometry, with two O atoms of two symmetry-related carboxyl-ate ligands in axial positions and three methyl groups in equatorial positions. In the crystal structure, carboxyl-ate bridges link the metal atoms, forming zigzag chains parallel to the b axis.

| S-EPMC3011523 | biostudies-literature

catena-Poly[[tri-n-butyl-tin(IV)]-?-2-thio-phene-acetato].

Project description:The title compound, [Sn(C(4)H(9))(3)(C(6)H(5)O(2)S)](n), possesses an infinite chain structure. The SnO(2)C(3) centre has a distorted trigonal-bipyramidal geometry (? = 0.145) with the O atoms in the axial positions. Atoms of the thio-phene group S1 and C4 are disordered over two sites The S atom and one C atom, with attached H atom, of the thiophene ring are disordered over two positions; the site occupancy factors are ca 0.7 and 0.3.

| S-EPMC2919292 | biostudies-literature

catena-Poly[[[diaqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato-[tetra-aqua-iron(II)]-μ-pyridine-2,5-dicarboxyl-ato] tetra-hydrate].

Project description:In the crystal structure of the title compound, {[Fe(2)(C(7)H(3)NO(4))(2)(H(2)O)(6)]·4H(2)O}(n), there are two types of coordination for the Fe(II) atoms. One Fe(II) atom is in a distorted octa-hedral N(2)O(4) environment, with two chelating rings from the pyridine-dicarboxyl-ate ligands and two O atoms from the water mol-ecules, while the other is in a distorted octa-hedral O(6) environment with two O atoms from the pyridine-dicarboxyl-ate ligands and four O atoms from the water mol-ecules. Both Fe(II) atoms lie on crystallographic centers of symmetry. The complex possesses an infinite chain structure running along the [101] direction. These chains are inter-connected by the uncoordinated water mol-ecules through O-H⋯O hydrogen bonds.

| S-EPMC2960407 | biostudies-literature

catena-Poly[[dimethyl-tin(IV)]-?-cis-cyclo-hexane-1,2-dicarboxyl-ato].

Project description:The title complex, [Sn(CH(3))(2)(C(8)H(10)O(4))](n), was synthesized from cis-cyclo-hexane-1,2-dicarboxylic acid and dimethyl-tin dichloride. The complex has a bridging bis-bidentate carboxyl-ate group resulting in a zig-zag chain structure parallel to [001]. The Sn atom is six-coordinated and displays a distorted octa-hedral geometry.

| S-EPMC2968691 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-cyclo-hex-3-ene-1-carboxyl-ato].

Project description:The title compound, [Sn(CH(3))(3)(C(7)H(9)O(2))](n), forms an extended zigzag chain structure propagating parallel to [010]. The Sn atom is in a slightly distorted trigonal-bipyramidal coordination environment with two carboxyl-ate O atoms in the axial and the three methyl groups in equatorial sites. The cyclo-hexene ring has a distorted half-boat conformation. There is an intra-molecular C-H?O hydrogen bond.

| S-EPMC2980015 | biostudies-literature

catena-Poly[[trimethyl-tin(IV)]-?-2,5-difluoro-benzoato-?O:O'].

Project description:In the title polymeric coordination compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the carboxyl-ate O atoms in the axial positions and the equatorial positions occupied by the methyl groups. The two Sn-O bond lengths are 2.225?(5) and 2.410?(6)?Å.

| S-EPMC2967876 | biostudies-other

Bis(triphenyl-stann-yl) thio-phene-2,5-dicarboxyl-ate.

Project description:Mol-ecules of the title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(2)O(4)S)], lie on inversion centres with the central thio-phene ring disordered equally over two orientations. The carboxyl-ate groups are approximately coplanar with the thio-phene ring [dihedral angle = 4.0?(1)°] and the Sn-O bond distance of 2.058?(4)?Å is comparable to that in related organotin carboxyl-ates.

| S-EPMC2969381 | biostudies-literature

catena-Poly[diimidazolium [bis-(?-pyridine-2,5-dicarboxyl-ato)bis-[diaqua-praseodymate(III)]]-bis-(?-pyridine-2,5-dicarboxyl-ato)].

Project description:The title compound {(C(3)H(5)N(2))(2)[Pr(2)(C(7)H(3)NO(4))(4)(H(2)O)(4)]}(n), has a chain structure featuring a dimeric unit consisting of two Pr(III) atoms within a dodecahedral environment. Each of the metal cations is coordinated by two N atoms and two O atoms from two pyridine-2,5-dicarboxyl-ate ligands, two O atoms from another two pyridine-2,5-dicarboxyl-ate ligands and two water O atoms. The Pr(III) ions are bridged by two ligands along the c axis, forming the dimeric unit, and these are connected by four ligands along the b axis, forming a chain. N-H?O and O-H?O hydrogen bonds are found in the structure.

| S-EPMC3089278 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data