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Catena-Poly[[trimethyl-tin(IV)]-?-5-methyl-thio-phene-2-carboxyl-ato-?O:O'].

ABSTRACT: In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].

SUBMITTER: Zhu Q

PROVIDER: S-EPMC3238733 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyl-tin(IV)]-μ-5-methyl-thio-phene-2-carboxyl-ato-κO:O'].

Zhu Qi Q Zhang Rufen R

Acta crystallographica. Section E, Structure reports online 20111125 Pt 12

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010]. ...[more]

PMID: 22199610

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