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Catena-Poly[[trimethyl-tin(IV)]-?-phenyl-seleninato-?O:O'].

ABSTRACT: In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.

SUBMITTER: Guo M

PROVIDER: S-EPMC3051585 | biostudies-literature | 2011 Jan

REPOSITORIES: biostudies-literature

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catena-Poly[[trimethyl-tin(IV)]-μ-phenyl-seleninato-κO:O'].

Guo Mengjie M Ru Jing J Zhang Rufen R

Acta crystallographica. Section E, Structure reports online 20110112 Pt 2

In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis. ...[more]

PMID: 21522835

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