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[N'-(1,3-Dioxoindan-2-yl-idene)-2-oxido-benzohydrazidato-κO,N,O]tripyridine-nickel(II) pyridine solvate.

ABSTRACT: In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol-ecules, forming a distorted octa-hedral geometry. The Ni-O(phenolate) bond [1.9750 (16) Å] is shorter than the Ni-O(carbon-yl) bond [2.0840 (16) Å] and the Ni-N bonds (mean 2.120 Å).

SUBMITTER: Liu WS

PROVIDER: S-EPMC2961996 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature

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[N'-(1,3-Dioxoindan-2-yl-idene)-2-oxido-benzohydrazidato-κO,N,O]tripyridine-nickel(II) pyridine solvate.

Liu Wei-Sheng WS Wu Da-Xiang DX Chen Jia-Yu JY Wang Hui-Juan HJ Tang Xiao-Liang XL

Acta crystallographica. Section E, Structure reports online 20080731 Pt 8

In the title compound, [Ni(C(16)H(8)N(2)O(4))(C(5)H(5)N)(3)]·C(5)H(5)N, the Ni(II) atom is six-coordinated by two O atoms and one N atom from the Schiff base ligand and by three N atoms from three pyridine mol-ecules, forming a distorted octa-hedral geometry. The Ni-O(phenolate) bond [1.9750 (16) Å] is shorter than the Ni-O(carbon-yl) bond [2.0840 (16) Å] and the Ni-N bonds (mean 2.120 Å). ...[more]

PMID: 21203066

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