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Tetra-imidazolium hexa-?(4)-oxido-dodeca-?(2)-oxido-dodeca-oxidohexa-arsenate(III)hexa-molybdenum(VI)cuprate(II).

ABSTRACT: The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N-H?O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra-molecular architecture.

SUBMITTER: Liu M

PROVIDER: S-EPMC2983113 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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Tetra-imidazolium hexa-μ(4)-oxido-dodeca-μ(2)-oxido-dodeca-oxidohexa-arsenate(III)hexa-molybdenum(VI)cuprate(II).

Liu Meiduo M Su Zhanhua Z Shang Yongchen Y

Acta crystallographica. Section E, Structure reports online 20100930 Pt 10

The title compound, (C(3)H(5)N(2))(4)[As(6)CuMo(6)O(30)], is made up of a centrosymmetric anionic cluster and four imidazolium cations. In the cluster, the central Cu(II) atom is six-coordinated and lies on an inversion center. Adjacent clusters are linked via N-H⋯O hydrogen bonds between the imidazole cations and polyoxidoanions into a three-dimensional supra-molecular architecture. ...[more]

PMID: 21587445

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