1,4-Diazo-niabicyclo-[2.2.2]octane bis-(2-chloro-benzoate).

ABSTRACT: The title compound, C(6)H(14)N(2) (2+)·2C(7)H(4)ClO(2) (-), contains trimeric units linked by N-H?O hydrogen bonds. The carboxyl-ate groups of the 2-chloro-benzoate anions form dihedral angles of 66.1?(1) and 76.1?(1)° with the respective chloro-benzene rings to which they are bound. The hydrogen-bonded trimers are arranged in layers in the (200) planes and the chloro-benzoate anions form edge-to-face inter-actions between layers, with dihedral angles of 61.9?(1) and 49.8?(1)° and centroid-centroid distances of 4.85?(1) and 4.65?(1)?Å, respectively, for two crystallographically distinct inter-actions.

SUBMITTER: Skovsgaard S 

PROVIDER: S-EPMC2962050 | biostudies-literature | 2008 Jul

REPOSITORIES: biostudies-literature