Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

1-Chloro-methyl-1,4-diazo-niabicyclo[2.2.2]octane tetra-chloridocuprate(II).

ABSTRACT: In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter-molecular N-H?Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2-) anion. The organic dication is distorted, as indicated by the N-C-C-N torsion angles, which range from 16.76?(4) to 19.54?(3)°.

SUBMITTER: Rong T

PROVIDER: S-EPMC3152011 | biostudies-literature | 2011 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

1-Chloro-methyl-1,4-diazo-niabicyclo[2.2.2]octane tetra-chloridocuprate(II).

Rong Tao T

Acta crystallographica. Section E, Structure reports online 20110611 Pt 7

In the crystal structure of the title compound, (C(7)H(15)ClN(2))[CuCl(4)], a weak inter-molecular N-H⋯Cl hydrogen bond is observed between the organic dication and the tetrahedral [CuCl(4)](2-) anion. The organic dication is distorted, as indicated by the N-C-C-N torsion angles, which range from 16.76 (4) to 19.54 (3)°. ...[more]

PMID: 21836880

Similar Datasets

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocuprate(II).

Project description:In the crystal structure of the title compound, (C(8)H(15)N(3))[CuCl(4)], the cations and anions, in which the Cu(II) atom is tetra-hedrally coordinated, are linked via N-H?Cl hydrogen bonds into chains that are elongated in the c-axis direction.

| S-EPMC3011750 | biostudies-literature

1,2-Dimethyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocuprate(II).

Project description:In the title compound, (C(8)H(18)N(2))[CuCl(4)], torsion angles on the ethyl-ene bridges of the 1,4-diazo-niabicyclo-[2.2.2]octane fragment are in the range 11.9?(5)-15.0?(5)° and the [CuCl(4)](2-) anion has a strongly distorted tetra-hedral geometry. The cation is connected to the anion via three-center N-H?Cl hydrogen bonds.

| S-EPMC3212112 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridomanganate(II).

Project description:In the crystal structure of the title compound, (C(8)H(15)N(3))[MnCl(4)], the Mn atom is coordinated by four chloride ligands in a slightly distorted tetra-hedral geometry. Each [MnCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H?Cl hydrogen bonds, forming chains parallel to [001].

| S-EPMC3009148 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocobaltate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CoCl(4)], the four chloride anions coordinate the Co(II) ion in a distorted tetra-hedral geometry. In the crystal, N-H?Cl hydrogen bonds link cations and anions into chains running along the c axis. The crystal packing is further stabilized by weak C-H?Cl and C-H?N inter-actions.

| S-EPMC3344387 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-chloridocadmate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CdCl(4)], four Cl atoms coordinate the Cd(II) atom in a slightly distorted tetra-hedral geometry. In the crystal, each [CdCl(4)](2-) anion is connected to the 1-cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane dications by N-H?Cl hydrogen bonds, forming chains parallel to [001]. C-H?Cl inter-actions also occur.

| S-EPMC3344406 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane tetra-bromidocadmate(II) monohydrate.

Project description:The metal atom in the anion of the title salt, (C(6)H(14)N(2))[CdBr(4)]·H(2)O, shows a slightly distorted tetra-hedral coordination. The water mol-ecule is involved in three hydrogen bonds, viz. one N-H?O and two O-H?Br, and an N-H?Br inter-action consolidates the three-dimensional network.

| S-EPMC2977123 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane tetra-bromidocuprate(II) monohydrate.

Project description:In the title monohydrated salt, (C(6)H(14)N(2))[CuBr(4)]·H(2)O, the copper(II) ion is coordinated by the four bromide ions in a flattened tetra-hedral geometry. In the crystal, the cations, anions and water mol-ecules inter-act via N-H⋯O, O-H⋯Br and N-H⋯Br hydrogen bonds, forming chains parallel to the b axis. The chains are further linked by O-H⋯Br hydrogen bonds into layers parallel to the bc plane.

| S-EPMC3051942 | biostudies-literature

1,4-Diazo-niabicyclo-[2.2.2]octane tetra-chloridozincate monohydrate.

Project description:In the title compound, (C(6)H(14)N(2))[ZnCl(4)]·H(2)O, the crystal packing is governed by an extensive three-dimensional network of N-H?Cl, N-H?O and O-H?Cl hydrogen bonds. The zinc(II) metal centre has a slightly distorted tetra-hedral coordination geometry.

| S-EPMC2977617 | biostudies-literature

1-Cyano-methyl-1,4-diazo-niabicyclo-[2.2.2]octane tetra-bromidocadmate(II).

Project description:In the title salt, (C(8)H(15)N(3))[CdBr(4)], four Br atoms coordinate the Cd(II) atom in a distorted tetra-hedral geometry. In the crystal, weak N-H?Br inter-actions connect the anion to three symmetry-related cations. The crystal structure also displays very weak C-H?Br inter-actions.

| S-EPMC3011683 | biostudies-other

1-Chloro-methyl-1,4-diazo-niabicyclo-[2.2.2]octane bis-(hexa-fluoro-phosphate).

Project description:In the crystal structure of the title compound, C(7)H(15)ClN(2) (2+)·2PF(6) (-), the cations and anions are linked by inter-molecular N-H⋯F hydrogen bonds.

| S-EPMC3051799 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data