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4-Chloro-N-[N-(6-methyl-2-pyrid-yl)car-bamo-thio-yl]benzamide.

ABSTRACT: In the title compound, C(14)H(12)ClN(3)OS, the short exocyclic N-C bond lengths indicate resonance in the thiourea part of the mol-ecule. The title compound is stabilized by an intra-molecular N-H⋯N hydrogen bond, which results in the formation of a six-membered ring. In addition, it shows a synperiplanar conformation between the thio-carbonyl group and the pyridine group. Inter-molecular N-H⋯S and C-H⋯O inter-actions are also present.

SUBMITTER: Binzet G

PROVIDER: S-EPMC2967990 | biostudies-literature |

REPOSITORIES: biostudies-literature

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2-Methyl-N-[(3-methyl-2-pyrid-yl)carbamothio-yl]benzamide.

Project description:In the title compound, C(15)H(15)N(3)OS, the thio-urea group is stabilized by an intra-molecular hydrogen bond between the carbonyl O atom and the thio-amide group. A C-H⋯N intramolecular hydrogen bond is also present. Mol-ecules are linked by inter-molecular N-H⋯O and C-H⋯S hydrogen bonds.

| S-EPMC2961265 | biostudies-literature

Crystal structure of (E)-4-{1-[2-(car-bamo-thio-yl)hydrazin-1-yl-idene]ethyl}phenyl 4-methyl-benzoate.

Project description:The asymmetric unit of the title compound, C17H17N3O2S, consists of two independent mol-ecules, A and B, with different conformations: in mol-ecule A, the dihedral angles between the central benzene ring and the pendant tolyl and carbamo-thio-ylhydrazono groups are 71.12 (9) and 5.95 (8)°, respectively. The corresponding angles in mol-ecule B are 50.56 (12) and 26.43 (11)°, respectively. Both mol-ecules feature an intra-molecular N-H⋯N hydrogen bond, which closes an S(5) ring. In the crystal, mol-ecules are linked by N-H⋯O, N-H⋯S and C-H⋯O hydrogen bonds, generating a three-dimensional network.

| S-EPMC4331904 | biostudies-literature

2-Iodo-N-(6-methyl-2-pyrid-yl)benzamide.

Project description:The asymmetric unit of the title compound, C(13)H(11)IN(2)O, comprises two crystallographically independent mol-ecules. The dihedral angles between the ring planes are 53.56?(9) and 72.14?(19)° in the two molecules. Pairs of inter-molecular N-H?N hydrogen bonds and I?O inter-actions link neighbouring mol-ecules into two different pairs of dimers, those involving N-H?N interactions having R(2) (2)(8) ring motifs. Short inter-molecular I?O [3.1458?(15)?Å] and I?N [3.4834?(16)?Å] contacts are present. The crystal structure is further stabilized by inter-molecular C-H?? inter-actions [3.565?(2) and 3.629?(2)?Å].

| S-EPMC2968040 | biostudies-literature

N-(2-Chloro-benzo-yl)-N'-(3-pyrid-yl)thio-urea.

Project description:In the mol-ecule of the title compound, C(13)H(10)ClN(3)OS, the dihedral angles between the plane through the thio-urea group and the pyridine and benzene rings are 53.08 (3) and 87.12 (3)°, respectively. The mol-ecules are linked by inter-molecular N-H⋯N hydrogen-bonding inter-actions to form a supra-molecular chain structure along the a axis. An intra-mol-ecular N-H⋯O hydrogen bond is also present.

| S-EPMC2962040 | biostudies-literature

N-[4-Chloro-2-methyl-6-(N-methyl-car-bam-oyl)phen-yl]-1-(3-chloro-2-pyrid-yl)-3-trifluoro-meth-yl-1H-pyrazole-5-carboxamide.

Project description:In the title compound, C(19)H(14)Cl(2)F(3)N(5)O(2), which shows insecticidal activity, the dihedral angle between the pyrazole and pyridine rings is 68.15 (16)°. In the crystal structure, the mol-ecules are linked by N-H⋯O and C-H⋯O hydrogen bonds and an intra-molecular N-H⋯O inter-action also occurs. The F atoms of the -CF(3) group are disordered over two sets of sites in a 0.800 (8):0.200 (8) ratio.

| S-EPMC2959817 | biostudies-literature

N-Benzoyl-N'-(2-chloro-3-pyrid-yl)thio-urea.

Project description:The title compound, C(13)H(10)ClN(3)OS, was prepared by the reaction of 3-amino-2-chloropyridine with benzoyl isothio-cyanate at room temperature. The thio-urea group makes dihedral angles of 47.17?(5) and 51.88?(4)°, respectively, with the benzene and pyridyl rings, while the angle between the benzene and pyridine rings is 8.91?(3)°. Inter-molecular hydrogen-bond inter-actions link neighbouring mol-ecules into an infinite supra-molecular structure.

| S-EPMC2977241 | biostudies-literature

3-Chloro-N-[N-(furan-2-carbon-yl)hydrazinocarbo-thio-yl]benzamide.

Project description:In the title compound C13H10ClN3O3S, the benzoyl group maintains its trans conformation against the thiono group about the C-N bond and the intra-molecular hydrogen bond between the benzoyl O atom and thio-amide H atom. In the crystal, N-H?O and C-H?O hydrogen bonds link the mol-ecules, forming chains along the b-axis direction. In addition, C-H?? inter-actions occur between a phenyl H atom and the furan ring.

| S-EPMC3790427 | biostudies-literature

N-(4-Chloro-phen-yl)-2-methyl-benzamide.

Project description:In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9?(7) and 46.4?(5)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is 83.1?(1)°. In the crystal structure, mol-ecules form chains running along the b axis through N-H?O hydrogen bonds.

| S-EPMC2968167 | biostudies-literature

4-Chloro-N-(3-methyl-phen-yl)benzamide.

Project description:In the title compound, C(14)H(12)ClNO, the meta-methyl substituent in the aniline ring is positioned anti to the N-H bond. The dihedral angle between the rings is 12.4?(1)°. The crystal structure is stabilized by inter-molecular N-H?O hydrogen bonds, which link the mol-ecules into C(4) chains running along the c-axis direction.

| S-EPMC3247319 | biostudies-literature

N-(2-Chloro-phen-yl)-4-methyl-benzamide.

Project description:The asymmetric unit of the title compound, C(14)H(12)ClNO, contains two independent mol-ecules in which the dihedral angles between the two aromatic rings are 51.76?(6) and 51.48?(7)°. The crystal structure is stabilized by inter-molecular N-H?O hydrogen bonds, which link the mol-ecules into chains running along the c axis.

| S-EPMC3201415 | biostudies-literature

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