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Morpholinium 2,4,6-trinitro-phenolate.

ABSTRACT: There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (-). The morpholinium cations in both mol-ecules are puckered and adopt a chair conformation. Intermolecular N-H?O and C-H?O inter-actions generate rings of motifs R(2) (1)(5) and R(1) (2)(6). The supra-molecular aggregation is completed by the presence of two co-operative hydrogen-bonded networks of further N-H?O inter-actions, which generate an infinite one-dimensional chain along the base vector [100]. Two C-H?? interactions are also seen.

SUBMITTER: Vembu N

PROVIDER: S-EPMC2968070 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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Morpholinium 2,4,6-trinitro-phenolate.

Vembu Nagarajan N Fronczek Frank R FR

Acta crystallographica. Section E, Structure reports online 20081220 Pt 1

There are two independent formula units in the asymmetric unit of the title compound, C(4)H(10)NO(+)·C(6)H(2)N(3)O(7) (-). The morpholinium cations in both mol-ecules are puckered and adopt a chair conformation. Intermolecular N-H⋯O and C-H⋯O inter-actions generate rings of motifs R(2) (1)(5) and R(1) (2)(6). The supra-molecular aggregation is completed by the presence of two co-operative hydrogen-bonded networks of further N-H⋯O inter-actions, which generate an infinite one-dimensional chain al ...[more]

PMID: 21581614

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