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Tris(1H-benzimidazol-3-ium-2-ylmeth-yl)amine tris-(2,4,6-trinitro-phenolate) acetonitrile disolvate.

ABSTRACT: In the cation of the title salt, C(24)H(24)N(7) (3+)·3C(6)H(2)N(3)O(7) (-)·2C(2)H(3)N, the three benzimidazolium ring systems are oriented to each other at dihedral angles of 10.42?(7), 23.98?(7) and 22.17?(7)°. In the crystal, the cation links to the adjacent picrate anions via N-H?O hydrogen bonds; one of independent acetonitrile solvent mol-ecules is also linked to the cation via an N-H?N hydrogen bond.

SUBMITTER: Bai Y

PROVIDER: S-EPMC3379477 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Tris(1H-benzimidazol-3-ium-2-ylmeth-yl)amine tris-(2,4,6-trinitro-phenolate) acetonitrile disolvate.

Bai Ying Y Yuan Jing-Kun JK Wang Hua H Pan Guo-Long GL Wu Hui-Lu HL

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the cation of the title salt, C(24)H(24)N(7) (3+)·3C(6)H(2)N(3)O(7) (-)·2C(2)H(3)N, the three benzimidazolium ring systems are oriented to each other at dihedral angles of 10.42 (7), 23.98 (7) and 22.17 (7)°. In the crystal, the cation links to the adjacent picrate anions via N-H⋯O hydrogen bonds; one of independent acetonitrile solvent mol-ecules is also linked to the cation via an N-H⋯N hydrogen bond. ...[more]

PMID: 22719675

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