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2-Fluoro-N-o-tolyl-benzamide.

ABSTRACT: In the title compound, C(14)H(12)FNO, the ortho-F atom and corresponding H atom on the fluoro-benzene ring are disordered over two positions with occupancies of 0.856?(4) and 0.144?(4). The amide unit is planar with a maximum deviation of 0.0057?(16)?Å and the amide plane makes dihedral angles of 38.27?(11)° with the fluoro-benzene ring plane and 37.53?(10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17?(15)°. In the crystal structure, chains form along b through N-H?O hydrogen bonds augmented by C-H?? inter-actions. Additional inter-molecular C-H?O and C-H?F hydrogen bonds further stabilize the structure, forming layers in the ac plane.

SUBMITTER: Saeed A

PROVIDER: S-EPMC2968107 | biostudies-literature | 2008 Dec

REPOSITORIES: biostudies-literature

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2-Fluoro-N-o-tolyl-benzamide.

Saeed Aamer A Khera Rasheed Ahmad RA Ameen Shahid S Simpson Jim J Stanley Roderick G RG

Acta crystallographica. Section E, Structure reports online 20081224 Pt 1

In the title compound, C(14)H(12)FNO, the ortho-F atom and corresponding H atom on the fluoro-benzene ring are disordered over two positions with occupancies of 0.856 (4) and 0.144 (4). The amide unit is planar with a maximum deviation of 0.0057 (16) Å and the amide plane makes dihedral angles of 38.27 (11)° with the fluoro-benzene ring plane and 37.53 (10)° with the tolyl ring. The two benzene rings are inclined at an angle of 4.17 (15)°. In the crystal structure, chains form along b through N- ...[more]

PMID: 21581656

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