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2,4-Dichloro-N-o-tolyl-benzamide.

ABSTRACT: In the title compound, C(14)H(11)Cl(2)NO, the central C-C(O)-N-C amide unit makes dihedral angles of 68.71?(11) and 54.92?(12)°, respectively, with the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 16.25?(17)°. In the crystal, N-H?O hydrogen bonds link mol-ecules into zigzag chains propagating in [001]. C-H?Cl contacts link these chains and additional C-H?O contacts generate stacks down b. Weak C-H?? and C-Cl?? inter-actions [Cl?centroid distance = 3.5422?(15)?Å] may also stabilize the structure.

SUBMITTER: Saeed A

PROVIDER: S-EPMC2969429 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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2,4-Dichloro-N-o-tolyl-benzamide.

Saeed Aamer A Khera Rasheed Ahmad RA Simpson Jim J Stanley Roderick G RG

Acta crystallographica. Section E, Structure reports online 20090620 Pt 7

In the title compound, C(14)H(11)Cl(2)NO, the central C-C(O)-N-C amide unit makes dihedral angles of 68.71 (11) and 54.92 (12)°, respectively, with the dichloro-benzene and tolyl rings. The two aromatic rings are inclined at 16.25 (17)°. In the crystal, N-H⋯O hydrogen bonds link mol-ecules into zigzag chains propagating in [001]. C-H⋯Cl contacts link these chains and additional C-H⋯O contacts generate stacks down b. Weak C-H⋯π and C-Cl⋯π inter-actions [Cl⋯centroid distance = 3.5422 (15) Å] may a ...[more]

PMID: 21582906

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