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Oxybis(dimesitylborane) dichloro-methane hemisolvate.


ABSTRACT: The title compound, C(36)H(44)B(2)O·0.5CH(2)Cl(2), contains an almost linear O-B-O linkage [177.23?(15)°] and approximately orthogonal [interplanar angles 89.49?(5) and 80.77?(4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem. Res. (S), p. 93]. Inter-molecular C-H?? inter-actions exist between mesityl groups, with a C-H?centroid separation of 3.6535?(18)?Å. The dichloromethane mol-ecules lie on twofold rotation axes.

SUBMITTER: Son JH 

PROVIDER: S-EPMC2968469 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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Oxybis(dimesitylborane) dichloro-methane hemisolvate.

Son Jung-Ho JH   Hoefelmeyer James D JD  

Acta crystallographica. Section E, Structure reports online 20090206 Pt 3


The title compound, C(36)H(44)B(2)O·0.5CH(2)Cl(2), contains an almost linear O-B-O linkage [177.23 (15)°] and approximately orthogonal [interplanar angles 89.49 (5) and 80.77 (4)°] trigonal planar B centers, consistent with the previously reported non-solvated structure [Cardinet al. (1983). J. Chem. Res. (S), p. 93]. Inter-molecular C-H⋯π inter-actions exist between mesityl groups, with a C-H⋯centroid separation of 3.6535 (18) Å. The dichloromethane mol-ecules lie on twofold rotation axes. ...[more]

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