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[1,5-Bis(4-fluoro-phen-yl)thio-carbazo-nato-?N,S]phenyl-mercury(II) dichloro-methane hemisolvate.

ABSTRACT: In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio-carbazo-nate ligands by 61.49?(10) and 67.79?(11)° in the two complex mol-ecules comprising the asymmetric unit. Important geometrical parameters include Hg-C = 2.079?(4) and 2.087?(4)?Å, Hg-S = 2.3869?(10) and 2.3889?(11)?Å, and C-Hg-S = 166.42?(12) and 168.09?(13)°. Weak intramolecular Hg-N bonding inter-actions of 2.589?(4) and 2.626?(4)?Å are observed. In the crystal, C-H?Cl, C-H?F, C-H?N, C-H?? and ?-? [centroid-centroid distances = 3.648?(3) and 3.641?(3)?Å] inter-actions, create parallel planes along [101].

SUBMITTER: von Eschwege KG

PROVIDER: S-EPMC3238751 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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[1,5-Bis(4-fluoro-phen-yl)thio-carbazo-nato-κN,S]phenyl-mercury(II) dichloro-methane hemisolvate.

von Eschwege Karel G KG Muller Fabian F Muller Alfred A

Acta crystallographica. Section E, Structure reports online 20111130 Pt 12

In the title compound, [Hg(C(6)H(5))(C(13)H(9)F(2)N(4)S)]·0.5CH(2)Cl(2), the Hg(C(6)H(5)) units are twisted out of the planes of the thio-carbazo-nate ligands by 61.49 (10) and 67.79 (11)° in the two complex mol-ecules comprising the asymmetric unit. Important geometrical parameters include Hg-C = 2.079 (4) and 2.087 (4) Å, Hg-S = 2.3869 (10) and 2.3889 (11) Å, and C-Hg-S = 166.42 (12) and 168.09 (13)°. Weak intramolecular Hg-N bonding inter-actions of 2.589 (4) and 2.626 (4) Å are observed. In ...[more]

PMID: 22199628

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