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2-(2-Ammonio-ethyl)pyridinium hexa-chloridorhenate(IV).

ABSTRACT: In the title anti-ferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5?K. The salt is stabilized by an extensive network of N-H?Cl and C-H?Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation-anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic inter-actions.

SUBMITTER: Kochel A

PROVIDER: S-EPMC2968471 | biostudies-literature | 2009 Feb

REPOSITORIES: biostudies-literature

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2-(2-Ammonio-ethyl)pyridinium hexa-chloridorhenate(IV).

Kochel Andrzej A

Acta crystallographica. Section E, Structure reports online 20090204 Pt 3

In the title anti-ferromagnetic material, (C(7)H(12)N(2))[ReCl(6)], the Néel temperature is observed at 5 K. The salt is stabilized by an extensive network of N-H⋯Cl and C-H⋯Cl hydrogen bonds, where hydrogen-bonded anion chains and characteristic cation-anion motifs are present. Similar systems play an important role in crystal engineering as hydrogen bonds that can transmit magnetic inter-actions. ...[more]

PMID: 21582039

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