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Bis(2-bromo-pyridinium) hexa-chlorido-stannate(IV).

ABSTRACT: The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. Hydrogen-bonding inter-actions of two kinds, viz. N-H?Cl-Sn and C-H?Cl-Sn, along with Cl?Br inter-actions [3.4393?(15)?Å], connect the ions in the crystal structure into two-dimensional supra-molecular arrays. These supra-molecular arrays are arranged in layers approximately parallel to (110) built up from anions inter-acting with six symmetry-related surrounding cations.

SUBMITTER: Ali BF

PROVIDER: S-EPMC2961104 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Bis(2-bromo-pyridinium) hexa-chlorido-stannate(IV).

Ali Basem Fares BF Al-Far Rawhi R Haddad Salim F SF

Acta crystallographica. Section E, Structure reports online 20080410 Pt 5

The asymmetric unit of the title compound, (C(5)H(5)BrN)(2)[SnCl(6)], contains one cation and one half-anion. The [SnCl(6)](2-) anion is located on an inversion center and forms a quasi-regular octa-hedral arrangement. Hydrogen-bonding inter-actions of two kinds, viz. N-H⋯Cl-Sn and C-H⋯Cl-Sn, along with Cl⋯Br inter-actions [3.4393 (15) Å], connect the ions in the crystal structure into two-dimensional supra-molecular arrays. These supra-molecular arrays are arranged in layers approximately paral ...[more]

PMID: 21202188

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