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Diaqua-bis(ciprofloxacinato)manganese(II) 2,2'-bipyridine solvate tetrahydrate.

ABSTRACT: In the crystal structure of the title compound {systematic name: diaquabis-[1-cyclo-propyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro-quinoline-3-carboxyl-ato]manganese(II) 2,2'-bi-pyridine solvate tetrahydrate}, [Mn(C(17)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O and one carboxyl-ate O atom of the two ciprofloxacin ligands are bound to the Mn(II) ion and occupy the equatorial positions, while the two aqua O atoms lie in the apical positions resulting in a distorted octa-hedral geometry. The crystal packing is stabilized by N-H?O and O-H?O hydrogen bonding interactions.

SUBMITTER: Wang YJ

PROVIDER: S-EPMC2969266 | biostudies-literature | 2009 Jun

REPOSITORIES: biostudies-literature

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Diaqua-bis(ciprofloxacinato)manganese(II) 2,2'-bipyridine solvate tetrahydrate.

Wang Yan-Jun YJ Wang Na N Hu Rui-Ding RD Lin Qiu-Yue QY Wang Yun-Yun YY

Acta crystallographica. Section E, Structure reports online 20090617 Pt 7

In the crystal structure of the title compound {systematic name: diaquabis-[1-cyclo-propyl-6-fluoro-4-oxo-7-(piperazin-1-yl)-1,4-dihydro-quinoline-3-carboxyl-ato]manganese(II) 2,2'-bi-pyridine solvate tetrahydrate}, [Mn(C(17)H(17)FN(3)O(3))(2)(H(2)O)(2)]·C(10)H(8)N(2)·4H(2)O, the pyridone O and one carboxyl-ate O atom of the two ciprofloxacin ligands are bound to the Mn(II) ion and occupy the equatorial positions, while the two aqua O atoms lie in the apical positions resulting in a distorted oc ...[more]

PMID: 21582711

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