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Trans-Diaqua-bis(2,2'-bipyridine-?N,N')ruthenium(II) bis-(trifluoro-methane-sulfonate).

ABSTRACT: The title compound, trans-[Ru(bpy)(2)(H(2)O)(2)](CF(3)SO(3))(2) (bpy = 2,2'-bipyridine, C(10)H(8)N(2)), crystallized from the decomposition of an aged aqueous solution of a dimeric complex of cis-Ru(bpy)(2) in 0.1 M triflic acid. The Ru(II) ion is located on a crystallographic inversion center and exhibits a distorted octa-hedral coordination with equivalent ligands trans to each other. The Ru-O distance is 2.1053?(16)?Å and the Ru-N distances are 2.0727?(17) and 2.0739?(17)?Å. The bpy ligands are bent, due to inter-ligand steric inter-actions between H atoms of opposite pyridyl units across the Ru center. The crystal structure exhibits an extensive hydrogen-bonding network involving the water ligands and the trifluoromethane-sulfonate counter-ions within two-dimensional layers, although no close hydrogen-bond inter-actions exist between different layers.

SUBMITTER: Jude H

PROVIDER: S-EPMC2959720 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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trans-Diaqua-bis(2,2'-bipyridine-κN,N')ruthenium(II) bis-(trifluoro-methane-sulfonate).

Jude Hershel H White Peter S PS Dattelbaum Dana M DM Rocha Reginaldo C RC

Acta crystallographica. Section E, Structure reports online 20081011 Pt 11

The title compound, trans-[Ru(bpy)(2)(H(2)O)(2)](CF(3)SO(3))(2) (bpy = 2,2'-bipyridine, C(10)H(8)N(2)), crystallized from the decomposition of an aged aqueous solution of a dimeric complex of cis-Ru(bpy)(2) in 0.1 M triflic acid. The Ru(II) ion is located on a crystallographic inversion center and exhibits a distorted octa-hedral coordination with equivalent ligands trans to each other. The Ru-O distance is 2.1053 (16) Å and the Ru-N distances are 2.0727 (17) and 2.0739 (17) Å. The bpy ligands a ...[more]

PMID: 21580841

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